Method for making coated article and coated article thereof

ABSTRACT

A method for making a coated article includes the steps of: providing a substrate; forming a copper-molybdenum target by a hot isostatic pressing process using copper powder and molybdenum powder; forming a copper-molybdenum alloy layer on the substrate by vacuum sputtering using the copper-molybdenum target. A coated article is also described.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is one of the three related co-pending U.S. patent applications listed below. All listed applications have the same assignee. The disclosure of each of the listed applications is incorporated by reference into the other listed applications.

Attorney Docket No. Title Inventors US 39195 METHOD FOR MAKING COATED HSIN-PEI ARTICLE AND COATED ARTICLE CHANG THEREOF et al. US 39196 METHOD FOR MAKING COATED HSIN-PEI ARTICLE AND COATED ARTICLE CHANG THEREOF et al. US 39197 METHOD FOR MAKING COATED HSIN-PEI ARTICLE AND COATED ARTICLE CHANG THEREOF et al.

BACKGROUND

1. Technical Field

The present disclosure relates to a method for making coated articles and a coated article formed by the method.

2. Description of Related Art

Alloy coatings may be applied on metal substrates by hot dipping processes or thermal spraying using alloy powder. Copper (Cu) and molybdenum (Mo) are widely used for excellent properties and low costs. However, stable Cu—Mo alloy for a hot dipping process or thermal spraying may be difficult to obtain because the Cu and Mo are smelted at a very high temperature, which may cause the Cu—Mo alloy to disintegrate and form a Cu phase and a Mo phase. When being quenched, the Cu phase and Mo phase will separate and thus Cu-Mo alloy cannot be formed.

Therefore, there is room for improvement within the art.

BRIEF DESCRIPTION OF THE FIGURES

Many aspects of the disclosure can be better understood with reference to the following figures. The components in the figures are not necessarily drawn to scale, the emphasis instead being placed upon clearly illustrating the principles of the disclosure. Moreover, in the drawings like reference numerals designate corresponding parts throughout the several views.

FIG. 1 is a cross-sectional view of an exemplary embodiment of a coated article.

FIG. 2 is an overhead view of an exemplary embodiment of a vacuum sputtering device.

DETAILED DESCRIPTION

Referring to FIG. 1, according to an exemplary embodiment, a method for making a coated article 10 may include the following steps:

A substrate 11 is provided. The substrate 11 may be made of stainless steel or copper alloy.

The substrate 11 is cleaned in an ultrasonic cleaning device (not shown) filled with ethanol or acetone and then dried.

A copper-molybdenum (Cu—Mo) alloy layer 13 may be magnetron sputtered on the pretreated substrate 11. Referring to FIG. 2, the substrate 11 may be positioned in a coating chamber 21 of a vacuum sputtering device 20. The coating chamber 21 is fixed with Cu—Mo targets 23.

The mass ratio between the Cu and Mo in the Cu—Mo target 23 may be about 1:4 to about 4:1. The Cu—Mo targets 23 may be formed by a method as follows:

Copper powder and molybdenum powder are mixed and positioned in a ball mill (not shown) to be grinded for about 120 min-200 min to get a mixture. The copper powder has a purity of more than 99.9% and an average particle size of about 10 μm -60 μm. The molybdenum powder has a purity of more than 99.9% and an average particle size of about 10 μm-40 μm. The mixture is then hot isostatic pressed to form a semi-finished product. The semi-finished product is sintered for about 3 hours to 5 hours at a temperature of about 1350° C. -1500° C. and then cooled to form the Cu—Mo targets 23.

The coating chamber 21 is evacuated to about 8.0×10⁻³ Pa. Argon (Ar) gas having a purity of about 99.999% may be used as a working gas and is fed into the coating chamber 21 at a flow rate of about 100 standard-state cubic centimeters per minute (sccm) to about 300 sccm. The internal temperature of the coating chamber 21 may be heated to about 120° C.-180° C. A power of about 8 kilowatt (kW)-15 kW is applied to the Cu—Mo targets 23, and the copper atoms and molybdenum atoms are sputtered off from the Cu—Mo targets 23 to deposit on the substrate 11 and form the Cu—Mo alloy layer 13. The temperature in the coating chamber 21 is much lower than the temperature for smelting Cu and Mo, so the Cu and Mo deposited on the substrate 11 in the exemplary embodiment will not phase separate, thus a Cu—Mo alloy layer 13 is formed. The Cu—Mo alloy layer 13 has a thickness of about 120 nm-200 nm. During the depositing process, the substrate 11 may have a bias voltage of about −100 V to about −200 V. Depositing of the Cu-Mo alloy layer 13 may take about 30 min-50 min.

FIG. 1 shows the coated article 10 formed by the exemplary method. The coated article 10 includes the substrate 11 and the Cu—Mo alloy layer 13 formed on a surface of the substrate 11. The substrate 11 may be made of stainless steel or copper alloy. The mass ratio between the Cu and Mo within the Cu—Mo alloy layer 13 may be about 1:4 to about 4:1. The Cu—Mo alloy layer 13 has a thickness of about 120 nm-200 nm. The Cu—Mo alloy layer 13 has excellent mechanical and electrical properties.

Specific examples of making the coated article 10 are described as follows. The process of cleaning the substrate 11 in these specific examples may be substantially the same as previously described so it is not described here again. Additionally, the magnetron sputtering process of forming the Cu—Mo alloy layer 13 in the specific examples are substantially the same as described above, and the specific examples mainly emphasize the different process parameters of making the coated article 10.

EXAMPLE 1

The substrate 11 is made of stainless steel.

Forming the Cu—Mo targets 23: copper powder having an average particle size of 30 μm-60 μm and molybdenum powder having an average particle size of 10 μm-40 μm are mixed with a mass ratio of 4:1 and positioned in a ball mill to be grinded for 200 min and then be hot isostatic pressed to form a semi-finished product; the semi-finished product is sintered for 5 hours at a temperature of 1350° C. and then cooled to form the Cu—Mo targets 23.

Sputtering to form the Cu—Mo alloy layer 13 on the substrate 11: the flow rate of Ar is 300 sccm; the substrate 11 has a bias voltage of −180 V; the Cu—Mo targets 23 are applied with a power of 8 kW; the internal temperature of the coating chamber 21 is 150° C.; sputtering of the Cu—Mo alloy layer 13 takes 30 min; the Cu—Mo alloy layer 13 has a thickness of 120 nm.

EXAMPLE 2

The substrate 11 is made of copper-zinc alloy, the copper within the copper-zinc alloy has a mass percentage of more than 70%.

Forming the Cu—Mo targets 23: copper powder having an average particle size of 30 μm-60 μm and molybdenum powder having an average particle size of 10 μm-40 μm are mixed with a mass ratio of 1:4 and positioned in a ball mill to be grinded for 120 min and then be hot isostatic pressed to form a semi-finished product; the semi-finished product is sintered for 3 hours at a temperature of 1500° C. and then cooled to form the Cu—Mo targets 23.

Sputtering to form the Cu—Mo alloy layer 13 on the substrate 11: the flow rate of Ar is 300 sccm; the substrate 11 has a bias voltage of −100 V; the Cu—Mo targets 23 are applied with a power of 15 kW; the internal temperature of the coating chamber 21 is 180° C.; sputtering of the Cu—Mo alloy layer 13 takes 50 min; the Cu—Mo alloy layer 13 has a thickness of 200 nm.

It is believed that the exemplary embodiment and its advantages will be understood from the foregoing description, and it will be apparent that various changes may be made thereto without departing from the spirit and scope of the disclosure or sacrificing all of its advantages, the examples hereinbefore described merely being preferred or exemplary embodiment of the disclosure. 

1. A method for making a coated article, comprising: providing a substrate; forming a copper-molybdenum target by a hot isostatic pressing process using copper powder and molybdenum powder; forming a copper-molybdenum alloy layer on the substrate by vacuum sputtering using the copper-molybdenum target.
 2. The method as claimed in claim 1, wherein mass ratio between the copper and molybdenum within the copper-molybdenum target is about 1:4 to about 4:1.
 3. The method as claimed in claim 1, wherein the copper powder and the molybdenum powder all have a purity of more than 99.9%, the copper powder has an average particle size of about 10 μm-60 μm, the molybdenum powder has an average particle size of about 10 μm-40 μm.
 4. The method as claimed in claim 3, wherein forming the copper-molybdenum target is carried out by hot isostatic pressing the copper powder and molybdenum powder for about 120 min-200 min and then sintering for about 3 hours to about5 hours at about 1350° C.-1500° C.
 5. The method as claimed in claim 1, wherein forming the copper-molybdenum alloy layer uses a magnetron sputtering process; uses argon as a working gas, the argon having a flow rate of about 100 sccm-300 sccm; the copper-molybdenum target is applied with a power of about 8 kW-15 kW; magnetron sputtering of the copper-molybdenum alloy layer is conducted at a temperature of about 120° C.-180° C. and takes about 30 min-50 min.
 6. The method as claimed in claim 5, wherein the copper-molybdenum alloy layer has a thickness of about 120 nm-200 nm.
 7. The method as claimed in claim 5, wherein the substrate has a bias voltage of about −100 V to about −200 V during sputtering of the copper-molybdenum alloy layer.
 8. The method as claimed in claim 1, further comprising a step of ultrasonic cleaning the substrate before forming the copper-molybdenum alloy layer.
 9. The method as claimed in claim 1, wherein the substrate is made of stainless steel or copper alloy.
 10. A coated article, comprising: a substrate; and a vacuum deposited copper-molybdenum alloy layer formed on the substrate.
 11. The coated article as claimed in claim 10, wherein the substrate is made of stainless steel or copper alloy.
 12. The coated article as claimed in claim 10, wherein mass ratio between the copper and molybdenum within the copper-molybdenum alloy layer is about 1:4 to about 4:1.
 13. The coated article as claimed in claim 10, wherein the copper-molybdenum alloy layer has a thickness of about 120 nm-200 nm.
 14. A coated article, comprising: a substrate; and a copper-molybdenum alloy layer formed on the substrate by vacuum sputtering.
 15. The coated article as claimed in claim 14, wherein the substrate is made of stainless steel or copper alloy.
 16. The coated article as claimed in claim 14, wherein mass ratio between the copper and molybdenum within the copper-molybdenum alloy layer is about 1:4 to about 4:1.
 17. The coated article as claimed in claim 14, wherein the copper-molybdenum alloy layer has a thickness of about 120 nm-200 nm. 